Preparation, Alignment, and Optical Properties of Soluble Poly(phenylacetylene)-Wrapped Carbon Nanotubes†

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Preparation, Alignment, and Optical Properties of Soluble Poly(phenylacetylene)-Wrapped Carbon Nanotubes†

Carbon nanotube-containing poly(phenylacetylenes) (NT/PPAs) are prepared by in situ polymerizations of phenylacetylene catalyzed by WCl6-Ph4Sn and [Rh(nbd)Cl]2 (nbd ) 2,5-norbornadiene) in the presence of the nanotubes. The NT/PPAs are characterized by GPC, NMR, UV, FL, TGA, SEM, TEM, and XRD, and it is found that the nanotubes in the NT/PPAs are helically wrapped by the PPA chains. The short n...

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ژورنال

عنوان ژورنال: Macromolecules

سال: 1999

ISSN: 0024-9297,1520-5835

DOI: 10.1021/ma981825k